2. The search for the de-vulcanisation.
The real “recycling” operation has a very long history where the final goal was, and still is, de-vulcanisation of rubber for re-vulcanisation in new compounds.
This recycling must be done in 2 steps:
First the size-down of the tire into small grains and then as 2nd step, the de-vulcanisation of these grains.
This process is done in a mechanical, thermal, chemical way. Several processes and several chemical agents exist.
The master question is: how can we know if “re-cycled” rubber is de-vulcanised?
Or in other words: When is it a re-active rubber?
The simple answer was given by many European rubber labs: “the proof is by eating the cake!”.
If a MD Rheometer test shows the traditional S curve, then there was a re-vulcanisation of the recycled rubber grains: the grains are re-active.